1st Time Builder Skin/Roofing Question

First I would like to thank everyone for the information on this site. I am sure the answer to my question is on these forums somewhere but I couldn't find it. I tried to skin the interior of the cabin with 5.2mil Luan and it didn't even come close to being able to bend in the 19" corner. I ended up breaking the sheet trying
. Instead I used 1/4inch Sintra(PVC sheeting) for the corner and the Luan for the straight lengths. I tested the outside corner radius with the same results. Is there a trick to getting the Luan to bend easier or perhaps an alternative for the skin. I really do not want to spend the money for aluminum. Thanks in advance for your responses. Check out my album for pics of my build so far! All comments and constructive criticisms are welcome.
http://tnttt.com/album_ ... er_id=6339

http://tnttt.com/album_ ... er_id=6339