Hi Dave, I cannot speak for the Polyurethane but Epoxy is superior to Polyester. Don't take my word for it.
From a
boatbuilding site that I use.
"Can I use polyester instead of epoxy?
No. If the plans specify epoxy, you should use that resin. Polyester does not bond properly to plywood and will delaminate.
What kind of resin should I use?
All our plans specify epoxy resin exclusively. Polyester or vinylester are not acceptable. Polyester does not bond properly to wood and is not sufficiently resistant to moisture. With polyester, water will find it?s way to the plywood and result in rot, not with epoxy. Use a quality marine epoxy like the one we sell in our kit: it does not cost more.
What is the shelf life of epoxy resin?
Epoxy has an almost unlimited shelf life. You can keep epoxy for years and it will be as good as the first day. In very cold weather, epoxy may crystallize. It will become liquid and clear after warming up and will have exactly the same properties. "
I would also like to add that your ply NEEDS to be totally dry to get a good bond with Polyester. Do you know the humidity of your ply?
I have plenty of Polyester in the shed, but just had to spend about $120 to get Epoxy for my trailer. There isn't any point in saving a few $$$ just to spend it all later trying to fix the trailer. I've never come across West Epoxy here in the UK, but I have seen it get a lot of praise in the boat building community.