epoxy using flexible agents tests with in

Okay we all know epoxy, esp when thick build ups is brittle. Well reading over at expo portal in the sawtooth ulnimited thread that he wishes the epoxy he bought was a little less brittle ( maybe a little sever of a statement ). And I bought uscomposites thicker epoxy and I have been doing adhesion tests with the foam ( dow 25 psi exp ) to the fiberglass skin I will be using trying to figure out a repeatable way to put just enough epoxy in the sandwich. My thicker spots at the edges where I got squeeze out are brittle but over 1/16 inch thick.
So I have a couple of samples of the epoxy to foam test pieces for a base line. I then started reading about flexible epoxys and what can be used to make them flexible. I found about one item from a guy in new hampshire, and talked to him. His stuff he uses for a few things, one to stop epoxy from curing on his spatulas and stuff. It can be used to make epoxy more flexible in low doses. Smooth on makes one they sell, they say it makes "some" of their epoxys cure flexible and give ratios, based on weight. Well that would work with their epoxys, but does not roll over to others. We have to test.
So I bought some of smooth ons stuff, its a commercial plasticizer not cheap but it seems like it will go a long ways. My first tests where 3 samples. Using a large syringe while this worked fine for measuring the epoxy and hardener it was a little too gross of a measure for the additive it turns out. My first 3 batches where 15 ml of epoxy 7.5 ml of hardener ( from here out the mix ) and from about 1.5 ml to 3 or so to 5 or so of the additive. As I said its was tough to get an exact ratio. Plus not very repeatable. My epoxy I bought is mixed by volume only.
Each mix was used to glue a piece of fiber glass sheet ( frp ) to the foam, spread out on plastic sheet and the cup turned over on non stick al foil. Smooth on says it extends pot life esp at higher ratios, I put each sample in front of my 500 watts quartz light to keep the temp up as my garage is dropping in to the 60s at night and I am not turning the heat on for tests. After a few hours they where all gelling nicely at probably 80 degree surface temp as they should.
23 hours later I looked at everything. All samples cured, the epoxy cured from a stiff but flexible ( but did crack when folded 180 degrees and squeezed ) to stiff fruit roll up depending on how much additive. So obviously much more flexible than needed. Then I move to the plastic sheet, they all seems to bond pretty well ( it was an amazon bubble shipping bag ) to it, but remained attached and flexible as I played with it. Next the important test, adhesion. Well I ripped every piece of the fiberglass off the foam, the joint held, the foam failed. It actually seemed to take a thicker layer of the foam ripped off then a straight epoxy test. I did not sand either the foam or fiberglass sheet ( I want worse case tests ) . I wonder if the plasticizer made it penetrate further into the foam, and I mean chemically, they do state it thins the epoxy.
So it seems the stuff did what I want, but way more than needed at the approx ratios I tried. None of which where exact, or very repeatable for small mixes. So I have another test going right now 15 ml epoxy 7.5 ml of hardener and 15 grams of the additive. 32 grams was about 1.5 ml of the hardener, so I am around .5 or .6 of a ml. Kind of hard to measure in a 100 ml syringe.
Either way based on what the current test does I will be using some of the additive when I make my panels. If this last test still seems too flexible I will just move down another 1/2 of what my ratio is. I will be making the panel that does my floor this weekend, the least structurally important panel. So I might use the 15 grams per 15 ml of epoxy mix or it might be 7.5 grams. I will see where the last test winds up. Either way I will in effect have one more test, the left over epoxy from the floor panel to decide on my final ratio for the wall and roof panels.
Over all I am happy with the additive, as it makes the epoxy not as brittle, still bonds well. And its not like I am depending the stiffness of the epoxy for strength. The two .055 thick skins and the foam when bonded is plenty strong enough.
So I have a couple of samples of the epoxy to foam test pieces for a base line. I then started reading about flexible epoxys and what can be used to make them flexible. I found about one item from a guy in new hampshire, and talked to him. His stuff he uses for a few things, one to stop epoxy from curing on his spatulas and stuff. It can be used to make epoxy more flexible in low doses. Smooth on makes one they sell, they say it makes "some" of their epoxys cure flexible and give ratios, based on weight. Well that would work with their epoxys, but does not roll over to others. We have to test.
So I bought some of smooth ons stuff, its a commercial plasticizer not cheap but it seems like it will go a long ways. My first tests where 3 samples. Using a large syringe while this worked fine for measuring the epoxy and hardener it was a little too gross of a measure for the additive it turns out. My first 3 batches where 15 ml of epoxy 7.5 ml of hardener ( from here out the mix ) and from about 1.5 ml to 3 or so to 5 or so of the additive. As I said its was tough to get an exact ratio. Plus not very repeatable. My epoxy I bought is mixed by volume only.
Each mix was used to glue a piece of fiber glass sheet ( frp ) to the foam, spread out on plastic sheet and the cup turned over on non stick al foil. Smooth on says it extends pot life esp at higher ratios, I put each sample in front of my 500 watts quartz light to keep the temp up as my garage is dropping in to the 60s at night and I am not turning the heat on for tests. After a few hours they where all gelling nicely at probably 80 degree surface temp as they should.
23 hours later I looked at everything. All samples cured, the epoxy cured from a stiff but flexible ( but did crack when folded 180 degrees and squeezed ) to stiff fruit roll up depending on how much additive. So obviously much more flexible than needed. Then I move to the plastic sheet, they all seems to bond pretty well ( it was an amazon bubble shipping bag ) to it, but remained attached and flexible as I played with it. Next the important test, adhesion. Well I ripped every piece of the fiberglass off the foam, the joint held, the foam failed. It actually seemed to take a thicker layer of the foam ripped off then a straight epoxy test. I did not sand either the foam or fiberglass sheet ( I want worse case tests ) . I wonder if the plasticizer made it penetrate further into the foam, and I mean chemically, they do state it thins the epoxy.
So it seems the stuff did what I want, but way more than needed at the approx ratios I tried. None of which where exact, or very repeatable for small mixes. So I have another test going right now 15 ml epoxy 7.5 ml of hardener and 15 grams of the additive. 32 grams was about 1.5 ml of the hardener, so I am around .5 or .6 of a ml. Kind of hard to measure in a 100 ml syringe.
Either way based on what the current test does I will be using some of the additive when I make my panels. If this last test still seems too flexible I will just move down another 1/2 of what my ratio is. I will be making the panel that does my floor this weekend, the least structurally important panel. So I might use the 15 grams per 15 ml of epoxy mix or it might be 7.5 grams. I will see where the last test winds up. Either way I will in effect have one more test, the left over epoxy from the floor panel to decide on my final ratio for the wall and roof panels.
Over all I am happy with the additive, as it makes the epoxy not as brittle, still bonds well. And its not like I am depending the stiffness of the epoxy for strength. The two .055 thick skins and the foam when bonded is plenty strong enough.