I knew I would get lots of opinions on this. Ray, I thought I could remember the post you made about the barn, but for some reason I could not find it. I am assuming that the product you used was tempered Masonite. That is the only one that is exterior rated.
Which ever material I choose, the edges are going to be concealed partially by wood trim, the rest with bondo and then coated with several coats of paint. I am not necessarily looking to be cheap, I just am looking for the best material for my roof that will give me the finish I am looking for.
I was inspired by Len's Slumber Coach, so I am planning a woody finish with a green top. Since its going to be painted, and my free time to devote to the build is scarce, looking for things that will require the minimum finish effort without compromising on form or function. Although I have thought I might use the hammered finish paint from Rustoleum for the final coat on the roof. I used it on my wheels and liked the way it looks, and it would hide any imperfections in the roof. Hmmmmm,

That may not be a bad idea.....
Tom