You might check out Sum's Popup Teardrop page in the hall of Fame, I think it has a steel frame.
The only problem I would see in using steel to frame the sides and roof is that it wouldn't insulate as well (the wood framing acts as a thermal break, the steel would transfer the cold). I would assume that insulation would be handy in Alaska

You could use steel, then attach 1/2" wood furring strips inside to give it a better thermal break, not to mention it would allow you to use thicker insulation.
As for attaching the skin, I have built enclosed motorcycle trailers and used large head pop rivits to hold the skin on. I have also seen people use sheet metal screws. If you have an aluminum skin over the wood, you could attach the wood with countersunk screws or rivits, then apply the aluminum over the wood like you would with a traditional frame.
On the inside, I am afraid you would have screw or rivit heads showing, I can't think of an easy way to install the plywood and hide the fasteners.